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This 2006 textbook discusses the fundamentals and applications of statistical thermodynamics for beginning graduate students in engineering and the physical sciences.
"Fundamentals of Classical and Statistical Thermodynamics" provides a comprehensive introduction to this pivotal subject. Starting from basics, the book begins with a thorough introduction to the field, providing concise definitions and an overview of thermodynamics and its applications. The book discusses the fundamentals of classical equilibrium thermodynamics, thermal physics, kinetic theory and statistical mechanics. This comprehensive coverage enables the reader to understand not only the interrelationships between these subjects but also encourages an ability to interpret the thermodynamic quantities and laws in terms of statistical mechanics. Beginning with a detailed discussion of the four laws of thermodynamics the text introduces more advanced topics in later chapters, such as applications of the first and second laws, free energy and chemical equilibria, and equilibrium statististical mechanics and applications. Uniquely, this text includes a large number of worked examples throughout, with a range of problems at the end of each chapter and their solutions all at the end of the book. The most fundamental concepts of the subject are emphasised throughout and new derivations of many of the standard formulae have been developed to avoid excessive mathematical rigour. "Fundamentals of Classical and Statistical Thermodynamics: " Provides a comprehensive introduction to the field, covering both classical and statistical thermodynamics. Includes numerous worked examples and end of chapter problems with answers provided at the back of the book. Covers the essentials of the subject combined with cutting-edge material such as non-linear chemical physics, critical phenomena and transport theory. Ensures the necessary mathematics are limited to simple derivatives and integrals. Suitable for all undergraduate students of physics, chemistry, materials science and engineering. Will also be an ideal reference book for those working within science and engineering.
Thermodynamics: Fundamentals and Applications is a 2005 text for a first graduate course in Chemical Engineering. The focus is on macroscopic thermodynamics; discussions of modeling and molecular situations are integrated throughout. Underpinning this text is the knowledge that while thermodynamics describes natural phenomena, those descriptions are the products of creative, systematic minds. Nature unfolds without reference to human concepts of energy, entropy, or fugacity. Natural complexity can be organized and studied by thermodynamics methodology. The power of thermodynamics can be used to advantage if the fundamentals are understood. This text's emphasis is on fundamentals rather than modeling. Knowledge of the basics will enhance the ability to combine them with models when applying thermodynamics to practical situations. While the goal of an engineering education is to teach effective problem solving, this text never forgets the delight of discovery, the satisfaction of grasping intricate concepts, and the stimulation of the scholarly atmosphere.
The book presents a clear and unique approach to statistical thermodynamics based on Shannon' measure of information, and provides applications to problems of interest in the life sciences. There is no other book which presents the fundamentals of statistical thermodynamics on Information theory, yet also includes many applications which usually do not feature in such textbooks.
This Is An Introductory Book Which Explains The Foundations Of The Subject And Its Application. It Is Intended Primarily For Graduate Students But May Provide Useful Information And Reading To Science And Engineering Students At All Levels. It Assumes That Readers Have Knowledge Of Basic Thermodynamics And Quantum Mechanics. With This, The Theory Has Been Developed In A Simple, Logical And Understandable Way. Some Applications Of Statistical Thermodynamics Have Been Described In Detail With Illustrative Solved Examples.There Are Two Basic Approaches In Statistical Mechanics; One Based On The Study Of Independent Particles In An Isolated System And The Other Based On The Concept Of Ensembles. In This Book Attempt Has Been Made To Take Advantage Of Both Approaches. While The Fundamental Concepts Have Been Developed By First Approach, Concept Of Ensembles Have Been Included To Bring Out The Importance Of This Concept In The Application Of Statistical Thermodynamics To Chemical Systems Where Interparticle Interactions Become Important.Part I Of The Book Deals With The Background Concepts, Fundamentals In Mathematics, Classical Mechanics, Quantum Mechanics And Thermodynamics Which Are Essential For Statistical Mechanics. Part Ii Covers Formalism Of Statistical Mechanism And Its Relation To Thermodynamics As Well As The Statistical Mechanics Of Ensembles, Quantum Statistics And Fluctuations. Part Iii Includes Chapters On The Applications Of The Formalism To Real Laboratory Chemical Systems. In This Part Additions Such As Imperfect Gases, Equilibrium Isotope And Kinetic Isotope Effects And Reactions At The Surfaces Have Been Made, In This Edition. Part Iv Is Also An Addition Which Covers Quantum Systems Such As Ideal Fermi Gas (Free Electrons In Metals), Photon Gas And Ideal Bose Gas (Helium Gas).
Statistical Thermodynamics: Fundamentals and Applications discusses the fundamentals and applications of statistical thermodynamics for beginning graduate students in the engineering sciences. Building on the Maxwell-Boltzmann method of step-by-step development of the subject, this book makes few presumptions concerning students, previous exposure to statistics, quantum mechanics or spectroscopy. The book begins with the fundamentals of statistical thermodynamics, pauses to recover needed knowledge from quantum mechanics and spectroscopy, and then moves on to applications involving ideal gases, the solid state and radiation. A full introduction to kinetic theory is provided, including its applications to transport phenomena and chemical kinetics. Modern applications, such as laser-based diagnostics, are also discussed. Each chapter is carefully written to address student difficulties in learning this challenging subject, which is fundamental to combustion, propulsion, transport phenomena, spectroscopic measurements and nanotechnology. Students are made comfortable with their new knowledge by the inclusion of both example and prompted homework problems.
This book is based on many years of teaching statistical and thermal physics. It assumes no previous knowledge of thermodynamics, kinetic theory, or probability---the only prerequisites are an elementary knowledge of classical and modern physics, and of multivariable calculus. The first half of the book introduces the subject inductively but rigorously, proceeding from the concrete and specific to the abstract and general. In clear physical language the book explains the key concepts, such as temperature, heat, entropy, free energy, chemical potential, and distributions, both classical and quantum. The second half of the book applies these concepts to a wide variety of phenomena, including perfect gases, heat engines, and transport processes. Each chapter contains fully worked examples and real-world problems drawn from physics, astronomy, biology, chemistry, electronics, and mechanical engineering.

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